H315: Causes skin irritation. H319: Causes serious eye irritation. H336: May cause drowsiness or dizziness. H351: Suspected of causing cancer.
Precautionary Statement(s)
P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P302 + P352: IF ON SKIN: Wash with plenty of water. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313: IF exposed or concerned: Get medical advice/ attention.
2 Organic halogenated solvents and solutions of organic halogen-containing substances: For strongly contaminated or mixed halogenated solvents container B: Caution: Do not use aluminium containers; in addition, in the case of water-containing chlorinated waste materials do not use stainless-steel containers (danger of leaks caused by corrosion).
Safety Information
Categories of danger
carcinogenic
Product Usage Statements
Storage and Shipping Information
Storage
Store at +2°C to +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RID
UN 1593 , 6.1, III
Declaration (transport by air) IATA-DGR
UN 1593 , 6.1, III
Declaration (transport by sea) IMDG-Code
UN 1593 , 6.1, III, Segregation Group: 10 (Liquid halogenated hydrocarbons)
Supplemental Information
Specifications
Purity (GC)
≥ 99.0 %
Identity (IR)
conforms
Appearance of the substance
conforms
Acidic substances
conforms
Acidity (HCl)
≤ 0.001 %
Density (d 20 °C/20 °C)
1.320 - 1.332
Density (d 25 °C/25 °C)
1.318 - 1.322
Refractive index (n 20/D)
1.423 - 1.425
Free chlorine (Cl)
conforms
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (Ethanol)
≤ 2.0 % (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (2-Methyl-2-buten)
≤ 0.03 % (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (Carbon tetrachloride (impurity A))
≤ 0.001 % (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (Chloroform (impurity B))
≤ 0.005 % (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (Total of impurities other than ethanol and 2-methyl-2-butene)
≤ 0.1 % (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC)(reportingthreshold)
≤ 0.005 % (v/v)
1,1-Dichloroethene (GC)
≤ 0.03 %
1,2-Dichloroethene (GC)
≤ 0.03 %
Other residual solvents (ICH Q3C)
excluded by manufacturing process
Evaporation residue
≤ 0.002 %
Water
≤ 0.020 %
Elemental impurity specifications have been set considering ICH Q3D (Guideline for Elemental Impurities). Class 1-3 elements are not likely to be present above the ICH Q3D option 1 limit, unless specified and indicated (*). The product is stabilized with about 50 ppm 2-Methyl-2-butene. Conforms to Ph Eur, BP, NF.
