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102447 Chloroform

102447
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Overview

Replacement Information

Key Specifications Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
67-66-3 200-663-8 CHCl₃ CHCl₃ 119.38 g/mol

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          Description
          Catalogue Number102447
          SynonymsTCM, Trichloromethane, Methane trichloride, Methyl trichloride
          DescriptionChloroform
          OverviewAccurate analytic results in UV/VIS and infrared spectroscopy depend on the use of very pure solvents for sample preparation. The Uvasol® solvents range has been specially designed for spectroscopy and other applications requiring solvents of the highest spectral purity. The refinement process allows a greater degree of security in applications and avoids misinterpretation of analytical results caused by traces of UV, IR and fluorescence contamination. Uvasol® solvents offer best UV transmittance. In all specifications the minimum transmittance for 5 typical wavelengths are identified. Furthermore the transmittance is specified in accordance with Reag. Ph Eur and ACS.
          References
          Product Information
          CAS number67-66-3
          EC index number602-006-00-4
          EC number200-663-8
          Hill FormulaCHCl₃
          Chemical formulaCHCl₃
          Molar Mass119.38 g/mol
          HS Code2903 13 00
          Structure formula ImageStructure formula Image
          Quality LevelMQ100
          Applications
          ApplicationChloroform for spectroscopy Uvasol®. CAS 67-66-3, chemical formula CHCl₃.
          Biological Information
          Physicochemical Information
          Boiling point61 °C (1013 hPa)
          Density1.48 g/cm3 (20 °C)
          Melting Point-63 °C
          Vapor pressure211 hPa (20 °C)
          Solubility8.7 g/l
          Dimensions
          Materials Information
          Toxicological Information
          LD 50 oralLD50 Rat 695 mg/kg
          LD 50 dermalLD50 Rabbit > 3980 mg/kg
          Safety Information according to GHS
          Hazard Pictogram(s) Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Statement(s)H302: Harmful if swallowed.
          H315: Causes skin irritation.
          H319: Causes serious eye irritation.
          H331: Toxic if inhaled.
          H351: Suspected of causing cancer.
          H361d: Suspected of damaging the unborn child.
          H372: Causes damage to organs through prolonged or repeated exposure.
          Precautionary Statement(s)P281: Use personal protective equipment as required.
          P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
          P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
          P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
          P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
          Signal WordDanger
          RTECSFS9100000
          Storage class6.1 D Non combustible, acute toxicity cat. 3 / toxic or substances with chronic effects
          WGKWGK 3 highly hazardous to water
          Disposal2
          Organic halogenated solvents and solutions of organic halogen-containing substances: For strongly contaminated or mixed halogenated solvents container B: Caution: Do not use aluminium containers; in addition, in the case of water-containing chlorinated waste materials do not use stainless-steel containers (danger of leaks caused by corrosion).
          Safety Information
          Hazard Symbols Hazard SymbolsHarmful
          Categories of dangerharmful, irritant, carcinogenic, toxic for reproduction
          R PhraseR 20/22-36/38-40-48/20-63
          Harmful by inhalation and if swallowed.Irritating to eyes and skin.Limited evidence of a carcinogenic effect.Harmful: danger of serious damage to health by prolonged exposure through inhalation.Possible risk of harm to the unborn child.
          S PhraseS 36/37
          Wear suitable protective clothing and gloves.
          Product Usage Statements
          Storage and Shipping Information
          StorageStore at +2°C to +30°C.
          Packaging Information
          Transport Information
          Declaration (railroad and road) ADR, RIDUN 1888 , 6.1, III
          Declaration (transport by air) IATA-DGRUN 1888 , 6.1, III
          Declaration (transport by sea) IMDG-CodeUN 1888 , 6.1, III, Segregation Group: 10 (Liquid halogenated hydrocarbons)
          Supplemental Information
          Specifications
          Purity (GC)≥ 99.0 %
          Evaporation residue≤ 0.0002 %
          Water≤ 0.01 %
          Color≤ 10 Hazen
          Acidity≤ 0.0002 meq/g
          Alkalinity≤ 0.0002 meq/g
          Fluorescence (as quinine at 254 nm)≤ 1.0 ppb
          Fluorescence (as quinine at 365 nm)≤ 1.0 ppb
          Transmission (at 245 nm)≥ 15 %
          Transmission (at 250 nm)≥ 50 %
          Transmission (at 255 nm)≥ 60 %
          Transmission (at 260 nm)≥ 85 %
          Transmission (from 270 nm)≥ 98 %
          Absorbance (at 245 nm)≤ 0.82
          Absorbance (at 250 nm)≤ 0.30
          Absorbance (at 255 nm)≤ 0.22
          Absorbance (at 260 nm)≤ 0.07
          Absorbance (from 270 nm)≤ 0.01
          The product is stabilized with about 1% ethanol.
          Meet the requirements of "Specific use spectroscopy" according ACS

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          Categories

          Analytics and Sample Preparation > Spectroscopy > Solvents for Spectroscopy, Uvasol®
          Reagents, Chemicals and Labware > Solvents > Solvents for Instrumental Organic Analysis > Solvents for Spectroscopy, Uvasol®
          Analytics and Sample Preparation > Spectroscopy > UV/VIS Spectroscopy > Solvents for UV/VIS Spectroscopy