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852287 | Fmoc-p-Bz-Phe-OH

852287
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      Overview

      Replacement Information

      Key Specifications Table

      CAS #Hill FormulaMolar Mass
      117666-96-3 C₃₁H₂₅NO₅ 491.53 g/mol

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          Glass bottle 1 g
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              Glas bottle pre packed 5 g
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              Description
              Catalogue Number852287
              Brand Family Novabiochem®
              Alternate Names
              • (S)-3-(4-Benzoyl-phenyl)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-propionic acid,4-Benzoyl-N-[(9H-fluoren-9-ylmethoxy)carbonyl]phenylalanine
              Background InformationFmoc-p-Bz-Phe-OH-OH is a useful tool for preparing photoactivatable peptide-based affinity probes [1]. On photolysis at 366 nm, Benzoylphenylalanine (Bpa) generates a biradical that has a preference for insertion into C-H bonds, particularly those of Leu, Val and Met side chains.

              The derivative can be introduced using standard coupling method such as PyBOP and is stable to conditions used in peptide chain extension. For the cleavage of Bpa containing peptide from the resin, the use of thiols and silanes should be avoided as dithioketal formation and reduction, respectively, have been observed.
              References
              Product Information
              CAS number117666-96-3
              Hill FormulaC₃₁H₂₅NO₅
              Molar Mass491.53 g/mol
              HS Code2924 29 98
              Structure formula Image
              Applications
              ApplicationFmoc-p-Bz-Phe-OH Fmoc-L-p-benzoylphenylalanine Novabiochem®. CAS 117666-96-3, molar mass 491.53 g/mol.
              Biological Information
              Physicochemical Information
              Dimensions
              Materials Information
              Toxicological Information
              Safety Information according to GHS
              Storage class10 - 13 Other liquids and solids
              WGKWGK 2 water endangering
              Safety Information
              Product Usage Statements
              Storage and Shipping Information
              StorageStore at +2°C to +8°C.
              Packaging Information
              Transport Information
              Supplemental Information
              Specifications
              Colour (visual)white to slight yellow to beige
              Appearance of substance (visual)powder
              Identity (IR)passes test
              Optical rotation α 25/D (c=1 in DMF)-31.0 - -27.0 °
              Assay (HPLC, area%)≥ 98.0 % (a/a)
              Solubility (1 mmole in 2 ml DMF)clearly soluble