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103132 | 1,4-Dioxane

103132
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      Overview

      Replacement Information

      Key Specifications Table

      CAS #EC NumberHill FormulaMolar Mass
      123-91-1 204-661-8 C₄H₈O₂ 88.11 g/mol

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      1031321000
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          Glass bottle 1 l
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          1031322500
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              Glass bottle 2.5 l
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              Description
              Catalogue Number103132
              SynonymsGlycolethylether, 1,4-Diethylene dioxide, 1,4-Dioxacyclohexane
              OverviewWith their high degree of UV transmittance, low particle count, low acidity and alkalinity and low evaporation residue level, LiChrosolv® solvents are ideal for reproducible separations. Since separations are normally carried out under gradient conditions in analytical HPLC, we offer solvents in "gradient grade" as well as "isocratic grade". This enables to minimize the gradient effect of the solvent involved.
              References
              Product Information
              CAS number123-91-1
              EC index number603-024-00-5
              EC number204-661-8
              Hill FormulaC₄H₈O₂
              Molar Mass88.11 g/mol
              HS Code2932 99 00
              Structure formula Image
              Applications
              Application1,4-Dioxane for liquid chromatography LiChrosolv®. CAS 123-91-1, pH 6 - 8 (500 g/l, H₂O, 20 °C). MSDS and product info below.
              Biological Information
              Physicochemical Information
              Boiling point101.5 °C (1013 hPa)
              Density1.03 g/cm3 (20 °C)
              Explosion limit1.7 - 25.2 %(V)
              Flash point11 °C
              Ignition temperature300 °C
              Melting Point12 °C
              pH value6 - 8 (500 g/l, H₂O, 20 °C)
              Vapor pressure41 hPa (20 °C)
              Dimensions
              Materials Information
              Toxicological Information
              LD 50 oralLD50 Rat 5200 mg/kg
              LD 50 dermalLD50 Rabbit 7600 mg/kg
              Safety Information according to GHS
              Hazard Pictogram(s)


              Hazard Statement(s)H225: Highly flammable liquid and vapour.
              H319: Causes serious eye irritation.
              H335: May cause respiratory irritation.
              H351: Suspected of causing cancer.
              EUH019: May form explosive peroxides.
              EUH066: Repeated exposure may cause skin dryness or cracking.
              Precautionary Statement(s)P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
              P240: Ground/bond container and receiving equipment.
              P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
              P308 + P313: IF exposed or concerned: Get medical advice/ attention.
              P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
              RTECSJG8225000
              Storage class3 Flammable liquids
              WGKWGK 2 water endangering
              Disposal3
              Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
              Safety Information
              Hazard Symbols Flammable
              Harmful
              Categories of dangerhighly flammable, irritant, carcinogenic
              R PhraseR 11-19-36/37-40-66
              Highly flammable.May form explosive peroxides.Irritating to eyes and respiratory system.Limited evidence of a carcinogenic effect.Repeated exposure may cause skin dryness or cracking.
              S PhraseS 9-16-36/37-46
              Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.Wear suitable protective clothing and gloves.If swallowed, seek medical advice immediately and show this container or label.
              Product Usage Statements
              Storage and Shipping Information
              StorageStore at +5°C to +30°C.
              Packaging Information
              Transport Information
              Declaration (railroad and road) ADR, RIDUN 1165 , 3, II
              Declaration (transport by air) IATA-DGRUN 1165 , 3, II
              Declaration (transport by sea) IMDG-CodeUN 1165 , 3, II
              Supplemental Information
              Specifications
              Purity (GC)≥ 99.8 %
              Identity (IR)conforms
              Evaporation residue≤ 2.0 mg/l
              Water≤ 0.02 %
              Acidity≤ 0.0002 meq/g
              Alkalinity≤ 0.0002 meq/g
              Transmission (at 245 nm)≥ 50 %
              Transmission (at 270 nm)≥ 80 %
              Transmission (from 300 nm)≥ 98 %
              Filtered by 0.2 µm filter

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              Categories

              Analytics and Sample Preparation > Analytical Chromatography > Mobile Phases for Chromatography > Solvents for Liquid Chromatography, LiChrosolv®
              Reagents, Chemicals and Labware > Solvents > Solvents for Instrumental Organic Analysis > Solvents for Liquid Chromatography, LiChrosolv®