106371 Sodium borohydride

106371
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      Overview

      Replacement Information

      Key Specifications Table

      CAS #EC NumberHill FormulaChemical FormulaMolar Mass
      16940-66-2 241-004-4 H₄BNa NaBH₄ 37.83 g/mol

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      1063710100
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          Glass bottle 100 g
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          Description
          Catalogue Number106371
          SynonymsSodium tetrahydridoborate
          References
          Product Information
          CAS number16940-66-2
          EC number241-004-4
          Hill FormulaH₄BNa
          Chemical formulaNaBH₄
          Molar Mass37.83 g/mol
          HS Code2850 00 20
          Applications
          ApplicationSodium borohydride for analysis. CAS No. 16940-66-2, EC Number 241-004-4.
          Biological Information
          Physicochemical Information
          Boiling point500 °C (decomposition)
          Density1.07 g/cm3 (20 °C)
          Explosion limit3.02 %(V)
          Flash point69 °C not applicable
          Ignition temperature220 °C
          Melting Point>360 °C (slow decomposition)
          pH value11 (10 g/l, H₂O, 20 °C)
          Vapor pressure<1 hPa (25 °C)
          Bulk density350 - 500 kg/m3
          Dimensions
          Materials Information
          Toxicological Information
          LD 50 oralLD50 Rat 160 mg/kg
          LD 50 dermalLD50 Rabbit 230 mg/kg
          Safety Information according to GHS
          Hazard Pictogram(s) Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Statement(s)H360FD: May damage fertility. May damage the unborn child.
          H260: In contact with water releases flammable gases which may ignite spontaneously.
          H301: Toxic if swallowed.
          H314: Causes severe skin burns and eye damage.
          EUH014: Reacts violently with water.
          Precautionary Statement(s)P201: Obtain special instructions before use.
          P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
          P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
          P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
          P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
          P402 + P404: Store in a dry place. Store in a closed container.
          Signal WordDanger
          RTECSED3325000
          Storage class4.3 Hazardous materials, which set free flammable gases upon contact with water
          WGKWGK 2 obviously hazardous to water
          Disposal26
          Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
          Safety Information
          Hazard Symbols Hazard SymbolsToxic
          Hazard SymbolsFlammable
          Hazard SymbolsCorrosive
          Categories of dangerhighly flammable, toxic, corrosive
          R PhraseR 60-61-25-14/15-34
          May impair fertility.May cause harm to the unborn child.Also toxic if swallowed.Reacts violently with water, liberating extremely flammable gases.Causes burns.
          S PhraseS 14-26-36/37/39-43-45-53
          Keep away from oxidising and acidic substances as well as heavy-metal compounds.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of fire, use sand. Never use water.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid exposure - obtain special instructions before use.
          Product Usage Statements
          Storage and Shipping Information
          StorageStorage temperature: no restrictions.
          Packaging Information
          Transport Information
          Declaration (railroad and road) ADR, RIDUN 1426 , 4.3, I
          Declaration (transport by air) IATA-DGRUN 1426 , 4.3, I
          Declaration (transport by sea) IMDG-CodeUN 1426 , 4.3, I
          Supplemental Information
          Specifications
          Assay (oxidimetric)≥ 96.0 %
          Identitypasses test
          Chloride (Cl)≤ 0.5 %
          Sulphate (SO₄)≤ 0.005 %
          Heavy metals (as Pb)≤ 0.005 %
          As (Arsenic)≤ 0.001 %
          Bi (Bismuth)≤ 0.0005 %
          Fe (Iron)≤ 0.005 %
          Hg (Mercury)≤ 0.00001 %
          Sb (Antimony)≤ 0.005 %
          Se (Selenium)≤ 0.0002 %

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          Categories

          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reduction Reagents
          Analytics and Sample Preparation > Spectroscopy > Certipur® Reference Materials for AAS and ICP > Auxiliaries for AAS
          Reagents, Chemicals and Labware > Inorganic Reagents > Instrumental Inorganic Analysis > Certipur® Standards, Reference Materials and Buffers > Certipur® Reference Materials for AAS and ICP > Auxiliaries for AAS
          Analytics and Sample Preparation > Reference Materials > Certipur® Reference Materials for AAS and ICP > Auxiliaries for AAS